David Bowie and Pet Shop Boys (1996)
In honour of receiving the Outstanding Contribution to Music award, David Bowie performed his then-current single Hallo Spaceboy with the Pet Shop Boys, who had remixed the track to give it a disco edge.
The duo then left the stage, leaving Bowie to perform Moonage Daydream with a full band, before he was joined by Gail Ann Dorsey, who shared singing duty with him on his Queen collaboration Under Pressure.