Dizzee Rascal and Florence and The Machine (2010)

A year after winning the BRITs Critics Choice award in 2009, Florence Welch returned to the BRITs to cover this Candi Staton classic with a rap twist from from London MC Dizzee Rascal.

The mix of Florence's haunting voice, the house beat and Dizzee's rapping produced the moment of the night.