The '5 Minutes' rapper met the famous couple at the BAFTAs and described them as ''very beautiful'', insisting they made me realise it is possible to be a star ''without become a real a-hole''.
Speaking to the Mail on Sunday newspaper's Event magazine, he said: ''I met Brad Pitt and Angelina Jolie at the BAFTAs.
''They're both very beautiful people, in every sense - the aesthetics are amazing - but I always looked for humility in these kinda stars and they really are humble people.
''They offer you hope that you can reach the heights of stardom without becoming a real a-hole.''
However, Tinie was less than impressed with Gary Barlow, insisting despite his talent ''as a songwriter'' he has lost respect for the Take That star after it emerged he'd been caught up in a tax avoidance scheme.
He insisted: ''That tax thing is a bit annoying. Actually, it makes me angry because I pay my taxes.
''Apparently there are people fighting Barlow's corner saying, 'Let him keep the money'.
''Like, really? I respect him as a songwriter but not as a taxpayer.''
The 1969 session, including the only known recording of 'Sunshine Woman' by the band, will be included on a re-issue of 'The Complete BBC Sessions'...
The 55 year old actor joined Chris Martin and co. on stage in New Jersey to perform 'Earth Angel' and 'Johnny B. Goode'.
Bjork Digital comes to London's Somerset House in September, along with a single live show at the Royal Albert Hall.
Kim Kardashian released an audio excerpt from a phone call between Kanye and Taylor Swift over the lyrics of 'Famous' - but if it was recorded...
There's very much a strength of conviction in remaining what you were, but arguably more so in becoming what you want to be.
The BBC drama starring Aidan Turner returns to BBC One on September 4th.
Guns N' Roses were detained at the Canadian border last week for gun possession but they're adamant the weapon didn't belong to them.