The 'Cheers (Drink to That)' hitmaker has sampled some of the guitar riffs from The Heavy rockers' 'Wherever I May Roam' track on 'Red Lipstick', which appears on the deluxe version of her new record.
The song - which was written/produced by the Bajan beauty, The Dream, William Kennard and Saul Milton, as well as James Hetfield and Lars Ulrich from the 'Enter Sandman' rockers - also features sound recordings from Chase & Status' 'Saxon', according to JustJared.com.
Jay-Z is set to appear on the brunette beauty's 'Talk That Talk' album, with the '99 Problems' hitmaker rapping on record's title track.
Producer Tor Erik Hermansen said: "We are very happy with the song and Jay's verse is crazy - same with Rihanna's part."
Ester Dean - who produced Rihanna's hit song 'What's My Name?' has writing/producing credits on the tracks on the album, which is set to be released on November 21.