The couple and Maddox, 10, Pax, seven, Zahara, six, Shiloh, five, and three-year-old twins Knox and Vivienne visited the Odeon cinema in Richmond, south west London, to watch the animated film starring Katy Perry and Neil Patrick Harris.
Meanwhile, Angelina and Brad are said to have enrolled some of their kids at a London primary school because his new movie 'World War Z', which has been shooting in Cornwall, Scotland and the British capital, has over-run.
A source told The Sun newspaper: "The children are home tutored in the United States. But wherever possible Brad and Angelina like to have them attend local schools to introduce them to the culture of each country."
Despite spending most of their time in their homes in the US, France and Italy, the Jolie-Pitt family have been enjoying their time in the UK, and last week Angelina enjoyed a shopping spree on London's famous King's Road.
An onlooker at the French Connection store - where she spent £1,300 in 15 minutes - said: "She was really friendly and humble. She signed an autograph for some young girls in the shop, and wouldn't let any of the staff help her to the car with her bags, joking that she 'had people to do that' for her."